Search results for "Stationary flow"
showing 2 items of 2 documents
Solidification behavior of the theta system 2-propanol/poly(n-butyl methacrylate) I. Influences of thermoreversible gelation on stationary flow
1994
Zero shear viscosities, η0, were determined by means of a magnetoviscometer for melts of poly(n-butyl methacrylate) (M = 8.7 to 450 kg/mol, T =53.5 to 200°C) and for concentrated solutions of the highest molecular weight sample in isopropanol (T = 34.8 to 131.5 °C). Master curves can be constructed in both cases if the reference temperature is set proportional to the gelation temperature of the particular fluid. Special intersegmental interactions (eventually leading to thermoreversible gelation) can above all be felt in η0 (T) and in M c , the critical molecular weight determined in plots of log η0 vs. log M. As the temperature is lowered, the behavior changes from WLF to Arrhenius, and M …
Nonstationary flow surface theory for modeling the viscoplastic behaviors of soils
2016
Abstract This paper presents a three-dimensional elastic viscoplastic model that can describe the time-dependent behaviors of soft clays. The constitutive model is formulated based on the nonstationary flow surface theory and incorporates new developments, including (i) an improved definition of the nonstationary flow surface that is capable of capturing the stress–strain behaviors under different loading paths, (ii) a unique stress–strain—viscoplastic-strain-rate equation that is able to explicitly describe the nonstationary flow surface, and (iii) a final stable state concept that identifies the final equilibrium state at the end of creep and stress relaxation, which is also used to simpl…